Homogeneous, Supramolecular and Bio-Inspired Catalysis

A [Pd2L4]4+ cage complex for n-octyl-β-d-glycoside recognition

Organic & Biomolecular Chemistry
A (Pd2L4)4+ cage complex for n-octyl-β-d-glycoside recognition

Xander Schaapkens, Eduard O. Bobylev, Joost N. H. Reek, and Tiddo J. Mooibroek
Org. Biomol. Chem., 2020, 18(25), 4734-4738

DOI: 10.1039/D0OB01081B

Abstract

The cage complex [Pd₂9₄]⁴⁺ (3′) binds n-octyl glycosides in DCM/DMSO (9 : 1) solution with K_a≈ 51 M⁻¹ for n-Oct-β-D-Glc and K_a ≈ 29 M⁻¹ for n-Oct-β-D-Gal.

Publications (Joost Reek)